This work's objective was to examine the mechanical response of model caramels under tension, specifically identifying the conditions triggering the transition from ductile to brittle behavior. Pre-trials having been completed, tensile velocity, caramel moisture content, and temperature were the factors adjusted in this investigation. Generally, a rise in velocity, a drop in temperature, and a decrease in moisture content led to a more rigid response, causing a transformation from ductile to a more brittle nature, stemming from diminished viscous components within the material and prolonged relaxation periods. Intervertebral infection Despite the fracture strain being significantly lower than the maximum plastic elongation in the ductile specimen, a near-equalization occurred at the vicinity of the ductile-brittle transition for our material. This study is the basis for a comprehensive investigation of the intricate deformation and fracture processes in viscoelastic food systems during cutting, incorporating numerical modeling techniques.
The research aimed to explore the effect of adding lupine flour (LF) on the glycemic index (GI) and glycemic load (GL), the physical characteristics, and the quality of cooked durum semolina pasta. Lupine flour (LF0-LF25) comprised 0-25% of the enriched pasta. A selected sample was composed of 75% and 20% oat-glucans, 5% vital gluten, and 20% millet flour, as well. Products containing 75% beta-glucans and 5% vital gluten experienced only a modest decline in their respective glycemic indices. Following the incorporation of 20% lupine flour, a substantial reduction in pasta glycemic index was observed. By incorporating 20% lupine flour, 20% beta-glucans, and 20% millet flour, the product showed the lowest glycemic index and load (GI = 33.75%, GL = 72%, respectively). Simultaneously, the lupine-flour-enhanced products exhibited a heightened concentration of protein, fat, ash, and dietary fiber. The addition of lupine flour, at a concentration of up to 20%, led to the production of functional foods with good cooking qualities.
The main, though least valued, by-product of Belgian endive cultivation is the forced chicory root. Still, they include molecules of significant industrial application, like caffeoylquinic acids (CQAs). The objective of this study is to evaluate accelerated solvent extraction (ASE) as a green approach for the recovery of chlorogenic acid (5-CQA) and 3,5-dicaffeoylquinic acid (3,5-diCQA), the predominant CQAs. A D-optimal design was used to explore how temperature and ethanol percentage affect their extraction. RSM (response surface methodology) was used to identify the optimum extraction parameters, which yielded 495,048 mg/gDM 5-CQA at 107°C with 46% ethanol and 541,079 mg/gDM 35-diCQA at 95°C with 57% ethanol. The extracts' antioxidant activity was further optimized through the application of RSM. At 115 Celsius and a 40% ethanol concentration, antioxidant activity was at its maximum, exceeding a value of more than 22 mg of Trolox per gram of DM. The correlation between antioxidant activity and the amount of CQAs was ultimately determined. FCR's bioactive compounds show the potential for use as bio-based antioxidants.
An organic medium was chosen for the enzymatic alcoholysis procedure, which produced 2-monoacylglycerol (2-MAG), with a high concentration of arachidonic acid. Solvent type and water activity (aw) were found to be substantial factors influencing the outcome of 2-MAG yield, as the results indicate. Optimum conditions resulted in the crude product within the t-butanol system containing 3358% 2-MAG. Employing a two-stage extraction procedure, beginning with an 85% ethanol aqueous solution and hexane, followed by dichloromethane and water, a highly pure sample of 2-MAG was successfully obtained. In a lipase-inactivated system, the effect of solvent type and water activity (aw) on 2-MAG acyl migration was studied using isolated 2-MAG as the substrate. The findings suggest that non-polar solvents promoted the acyl migration of 2-MAG, contrasting with the inhibitory effect of polar solvent systems on isomerization. At 0.97, the aw prominently inhibited 2-MAG isomerization, while concurrently affecting both the hydrolysis of glycerides and lipase selectivity.
The spicy annual plant, Basil (Ocimum basilicum L.), is generally utilized as a flavoring agent in food. Due to the presence of polyphenols, phenolic acids, and flavonoids, basil leaves exhibit pharmaceutical properties. This work involved the extraction of bioactive compounds from basil leaves with carbon dioxide as the extraction agent. The most efficient extraction method, utilizing supercritical CO2 at 30 MPa and 50°C for two hours with 10% ethanol as a co-solvent, performed comparably to the 100% ethanol control. This method was successfully applied to both the Italiano Classico and Genovese basil cultivars. The extracts produced by this process were evaluated for their antioxidant activity, phenolic acid content, and volatile organic compounds. In both cultivar types, supercritical CO2 extraction demonstrated antioxidant properties (as measured by the ABTS+ assay), with significantly higher levels of caffeic acid (169-192 mg/g), linalool (35-27%), and bergamotene (11-14%) compared to the control group. Three assays indicated higher polyphenol content and antiradical activity in the Genovese cultivar than in the Italiano Classico cultivar, while the linalool content was considerably greater (3508%) in the Italiano Classico cultivar. PX-478 mw The supercritical CO2 extraction process yielded extracts replete with bioactive compounds, while also decreasing the consumption of ethanol, contributing to a more sustainable approach.
A comprehensive investigation into the bioactive compounds within papaya (Carica papaya) fruit was conducted, focusing on its antioxidant and anti-inflammatory properties. Korea's greenhouse-grown 'Tainung No. 2' papayas, after being harvested at differing ripenesses, were processed into seed and peel-pulp portions. Spectrophotometry determined total phenolic and flavonoid concentrations, and HPLC-DAD, utilizing fifteen standards, enabled the relative quantification of individual phenolic compounds, with a focus on comparative analysis. Antioxidant measurements were performed using four assays, namely DPPH (2,2-diphenyl-1-picrylhydrazyl), ABTS (2,2'-azino-bis(3-ethylbenzothiazoline-6-sulfonic acid)), FRAP (ferric reducing antioxidant power), and the inhibition of lipid peroxidation. By measuring the levels of reactive oxygen species (ROS) and nitric oxide (NO), the extent of oxidative stress was correlated with the anti-inflammatory activities of the regulated NF-κB signaling pathways. Ripening contributed to a rise in total phenol content in both seed and peel-pulp extracts, with flavonoid content showing an increase only within the seed extracts. There exists an association between total phenolic contents and ABTS radical scavenging activity, as well as FRAP. From a collection of fifteen phenolic compounds, the papaya extracts yielded chlorogenic acid, cynarin, eupatorine, neochlorogenic acid, and vicenin II. targeted medication review Papaya extracts effectively suppressed the production of ROS and NO. Especially, ripe seed extracts did not exhibit production inhibition, surpassing that of other extracts, which likely indicates a reduced suppression of NF-κB activation and iNOS expression. Based on these results, papaya fruit extracts, composed of seeds, peels, and pulps, are potentially suitable raw materials for crafting functional foods.
Dark tea, a distinctive microbial-fermented tea acclaimed for its potential anti-obesity effects, yet the specific contribution of microbial fermentation to the anti-obesity properties of the tea leaves remains largely unknown. A comparative analysis of microbial-fermented Qingzhuan tea (QZT) and unfermented Qingmao tea (QMT) was undertaken to evaluate their anti-obesity effects and their impact on gut microbiota. Our results indicated a similar anti-obesity effect for QMT extract (QMTe) and QZT extract (QZTe) in mice consuming a high-fat diet (HFD), but QZTe showed a substantially greater hypolipidemic improvement than QMTe. Microbiome examination indicated a greater ability of QZTe than QMTe to modulate the dysbiosis in the gut microbiota caused by a high-fat diet. Substantial augmentation of Akkermansiaceae and Bifidobacteriaceae, which have a negative correlation with obesity, was observed following QZTe treatment, whereas QMTe and QZTe treatments resulted in a significant reduction of Faecalibaculum and Erysipelotrichaceae, exhibiting a positive correlation with obesity. From a Tax4Fun analysis of QMTe/QZTe-altered gut microbiota, QMTe supplementation significantly reversed the HFD-induced increase in glycolysis and energy metabolism, whereas QZTe supplementation noticeably recovered the HFD-linked decrease in pyruvate metabolism. Microbial fermentation of tea leaves, while not significantly boosting anti-obesity effects, did demonstrably improve their hypolipidemic activity. QZT may effectively counteract obesity and its accompanying metabolic problems by beneficially influencing the gut's microbial composition.
The climacteric nature of mango fruits is a primary driver of postharvest deterioration, a crucial factor restricting storage and preservation. The storage attributes of two mango varieties and their response to 1000 mol L-1 melatonin treatment were evaluated in this study with the aim of determining its role in delaying fruit decay and boosting fruit physiological and metabolic processes, and gene relative expression, while under cold storage conditions. In both mango cultivars, MT treatment demonstrably deferred the onset of weight loss, firmness decline, respiration rate reduction, and decay development. Nevertheless, the TSS, TA, and TSSTA ratio remained unaffected by MT, irrespective of the cultivar type. Moreover, MT played a role in stopping the decrease in total phenol and flavonoid concentrations and AsA levels, and in slowing the increase in MDA content during storage for mangoes in both cultivars. Additionally, MT profoundly hampered the functional capacity of the PPO enzyme.